You can inscribe a tetrahedron in a dodecahedron. If you inscribe five, one at each vertex of the topmost face, you create a beautiful solid.
Tape five vertices together as shown. Place the tape on the inside of the model. Use one vertex of each color if you are making a multi-color model.
Richard Otis created this model using a different color for each tetrahedron. This helps you visualize how the tetrahedra are arranged.
The shape of each face can be constructed as shown.